07/03/2010
Update: Post now resides at new blog site! http://www.tcscblog.com/2010/11/30/add-bcc-recipient-in-sharepoint-designer-2010-workflow-e-mails/
When you design your email in SharePoint Designer workflows, you do not get the opportunity to include blind carbon-copy recipients. Here is the initial screenshot:
In order to add BCC, you need to click Advanced Properties located in the ribbon UI:
This will launch a separate window where you can now set your BCC recipients.
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SharePoint Adam 
02/24/2013 at 8:04 pm
simple and worked like a charm.